Organocatalytic enantioselective Friedel–Crafts aminoalkylation of indoles in the carbocyclic ring.

DOI Number:

10.1021/acscatal.6b00260

Reaction Category:

RXNO ID:

RXNO_0000369

Educt:

4-hydroxyindole, tert-butyl (E)-(1-methyl-2-oxoindolin-3-ylidene)carbamate

Product:

tert-butyl (R)-(3-(4-hydroxy-1H-indol-5-yl)-1-methyl-2-oxoindolin-3-yl)carbamate

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4- [[(8α,9S)-6′-methoxycinchonan-9-yl]amino]- 3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Cas No:

130-95-0