Fluoromethylation, methyl 2-(((tert-butoxycarbonyl)oxy)(3-chlorophenyl)methyl)acrylate, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide, methyl 3-(3-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)-3lambda3-butanoate, 1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione, Dihydroquinidine Derivative

Asymmetric Allylic Monofluoromethylation and Methylation of Morita–Baylis–Hillman Carbonates with FBSM and BSM by Cooperative Cinchona Alkaloid/FeCl2 Catalysis.

DOI Number:

10.1002/ange.201103748

Link to literature

Reaction Category:

Fluorination | Fluoromethylation

MOP ID:

MOP_0000553

Educt:

methyl 2-(((tert-butoxycarbonyl)oxy)(3-chlorophenyl)methyl)acrylate, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide

Product:

methyl 3-(3-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)-3lambda3-butanoate

Catalyst:

1,4-Bis[(9S)-10,11-dihydro-6′-methoxycinchonan-9-yl]-9,10-anthracenedione

Cas No:

176298-44-5



Associated Product from Buchler GmbH:

Dihydroquinidine Base

Cas No:

1435-55-8