Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon-Assisted CF Bond Cleavage.

DOI Number:

10.1002/anie.201308071

Reaction Category:

Educt:

allyl fluorides, trimethyl(perfluorophenyl)silane

Product:

allyl fluorides, allyl pentafluorobenzene

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7