Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon-Assisted CF Bond Cleavage.
DOI Number:
10.1002/anie.201308071
Reaction Category:
MOP ID:
MOP_0000553
Educt:
allyl fluorides, trimethyl(perfluorophenyl)silane
Product:
allyl fluorides, allyl pentafluorobenzene
Catalyst:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7
Associated Product from Buchler GmbH:
1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)
Cas No:
140853-10-7