Cinchona alkaloid catalyzed enantioselective fluorination of allyl silanes, silyl enol ethers, and oxindoles.
DOI Number:
10.1002/anie.200800717
Reaction Category:
MOP ID:
MOP_0000553
Educt:
((2-(4-chlorobenzyl)-1H-inden-3-yl)methyl)trimethylsilane, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide
Product:
(R)-2-(4-chlorobenzyl)-2-fluoro-1-methylene-2,3-dihydro-1H-indene
Catalyst:
(8α,9R)-(8′′α,9′′R)-9,9′′-[(2,5-Diphenyl-4,6-pyrimidinediyl)bis(oxy)]-bis[10,11-dihydro-6′-methoxycinchonan]
Cas No:
149820-65-5
Associated Product from Buchler GmbH:
DIhydroquinine Base
Cas No:
522-66-7