Designing Fluorinated Cinchona Alkaloids for Enantioselective Catalysis: Controlling Internal Rotation by a Fluorine‐Ammonium Ion gauche Effect (φNCCF).

DOI Number:

10.1002/chem.201102859

Reaction Category:

Educt:

substituted 1-oxo-2,3-dihydro-1H-indene-2-carboxylate, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide

Product:

substituted 2-fluoro-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Catalyst:

(9S)-9-fluoro-6′-methoxy-1-(phenylmethyl)-cinchonanium chloride

Cas No:

1374425-52-1

Cas No:

56-54-2