Catalytic Enantioselective Fluorination of β-Keto Esters by Phase-Transfer Catalysis Using Chiral Quaternary Ammonium Salts.
DOI Number:
10.1021/ol010281v
Reaction Category:
MOP ID:
MOP_0000553
Educt:
methyl 1-oxo-2,3-dihydro-1H-indene-2-carboxylate, (fluoromethylenedisulfonyl)dibenzene
Product:
methyl (R)-2-fluoro-1-oxo-2,3-dihydro-1H-indene-2-carboxylate
Catalyst:
(9S)-1-[[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]methyl]-9-(2-propynyloxy)-cinchonanium bromide
Cas No:
405506-35-6
Associated Product from Buchler GmbH:
Cinchonine Base
Cas No:
118-10-5