Catalytic Enantioselective Fluorination of β-Keto Esters by Phase-Transfer Catalysis Using Chiral Quaternary Ammonium Salts.

DOI Number:

10.1021/ol010281v

Reaction Category:

MOP ID:

MOP_0000553

Educt:

methyl 1-oxo-2,3-dihydro-1H-indene-2-carboxylate, (fluoromethylenedisulfonyl)dibenzene

Product:

methyl (R)-2-fluoro-1-oxo-2,3-dihydro-1H-indene-2-carboxylate

Catalyst:

(9S)-1-[[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]methyl]-9-(2-propynyloxy)-cinchonanium bromide

Cas No:

405506-35-6

Cas No:

118-10-5