Catalytic Enantioselective Fluorination of o-Cyano Esters by Phase-Transfer Catalysis Using Chiral Quaternary Ammonium Salts.

DOI Number:

Reaction Category:

MOP ID:

MOP_0000553

Educt:

4-nitrobenzyl 2-cyano-2-phenylacetate, (fluoromethylenedisulfonyl)dibenzene

Product:

4-nitrobenzyl (R)-2-cyano-2-fluoro-2-phenylacetate

Catalyst:

(9S)-1-[[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]methyl]-9-(2-propynyloxy)-cinchonanium bromide

Cas No:

405506-35-6

Cas No:

118-10-5