Dynamic kinetic resolution of biaryl lactones via a chiral bifunctional amine thiourea-catalyzed highly atropo-enantioselective transesterification.

DOI Number:

10.1021/jacs.6b03609

Reaction Category:

Educt:

biaryl lactones, alcohols

Product:

2'-hydroxy-[1,1'-biphenyl]-2-carboxylate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Cas No:

130-95-0