Phthalimide-based-SSCF 3 reagent for enantioselective dithiotrifluoromethylation.

DOI Number:

10.1039/D1QO00001B
Link to literature

Reaction Category:

Trifluoro-methylthiolation

Educt:

(3s,5s,7s)-adamantan-1-yl 5-methoxy-1-oxo-2,3-dihydro-1H-indene-2-carboxylate, 2-((trifluoromethyl)sulfinothioyl)isoindoline-1,3-dione

Product:

(3S,5S,7S)-adamantan-1-yl (R)-5-methoxy-1-oxo-2-((S)-(trifluoromethyl)sulfinothioyl)-2,3-dihydro-1H-indene-2-carboxylate

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7
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Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7