Enantioselective remote C–H activation directed by a chiral cation.
DOI Number:
10.1126/science.aba1120
Reaction Category:
Educt:
N-benzhydryl-2,2,2-trifluoroacetamide, Bis(pinacolato)diborane, hydrogen peroxide
Product:
(S)-2,2,2-trifluoro-N-((3-hydroxyphenyl)(phenyl)methyl)acetamide
Catalyst:
Bis(1,5-cyclooctadiene)dimethoxydiiridium, (8α,9R)-10,11-dihydro-9-hydroxy-6′-methoxy-1-[[3,3′′,5,5′′-tetrakis(1,1-dimethylethyl)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]-Cinchonanium 5′-methyl[2,2′-bipyridine]-5-methanesulfonate
Cas No:
2437404-33-4
Associated Product from Buchler GmbH:
Dihydroquinine Base
Cas No:
522-66-7