Enantioselective remote C–H activation directed by a chiral cation.

DOI Number:

10.1126/science.aba1120

Reaction Category:

Educt:

N-benzhydryl-2,2,2-trifluoroacetamide, Bis(pinacolato)diborane, hydrogen peroxide

Product:

(S)-2,2,2-trifluoro-N-((3-hydroxyphenyl)(phenyl)methyl)acetamide

Catalyst:

Bis(1,5-cyclooctadiene)dimethoxydiiridium, (8α,9R)-10,11-dihydro-9-hydroxy-6′-methoxy-1-[[3,3′′,5,5′′-tetrakis(1,1-dimethylethyl)[1,1′:3′,1′′-terphenyl]-5′-yl]methyl]-Cinchonanium 5′-methyl[2,2′-bipyridine]-5-methanesulfonate

Cas No:

2437404-33-4

Cas No:

522-66-7