Catalytic Atropenantioselective Heteroannulation between Isocyanoacetates and Alkynyl Ketones: Synthesis of Enantioenriched Axially Chiral 3‐Arylpyrroles.

DOI Number:

10.1002/anie.201812654
Link to literature

Reaction Category:

[3+2] Annulation | Atropisomer synthesis | Cyclization | Further Cyclizations

Educt:

Isocyanoacetates, alkynyl ketones

Product:

axially chiral 3‐Arylpyrroles

Catalyst:

silver oxide, 2-(diphenylphosphino)-N-[(8α,9S)-6′-methoxycinchonan-9-yl]-benzamide

Cas No:

1630973-03-3

Associated Product from Buchler GmbH:

Quinine Base

Cas No:

130-95-0