Enantioselective Synthesis of Tertiary α-Hydroxy Phosphonates Catalyzed by Carbohydrate/Cinchona Alkaloid Thiourea Organocatalysts.

DOI Number:

10.1002/anie.201204287

Reaction Category:

MOP ID:

MOP_0000597

Educt:

α-ketophosphonates, trimethylsilyl cyanide

Product:

tertiary α-hydroxy phosphonates

Catalyst:

N-[(8α,9S)-6′-Methoxycinchonan-9-yl]-N′-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-thiourea

Cas No:

1402349-85-2

Cas No:

130-95-0