Organocatalytic Asymmetric Halogenation/Semipinacol Rearrangement: Highly Efficient Synthesis of Chiral α-Oxa-Quaternary β-Haloketones.

DOI Number:

10.1021/ja201794v
Link to literature

Reaction Category:

Chlorination | Semipinacol Rearrangement

MOP ID:

MOP_0000551

Educt:

2-oxa allylic alcohols, 1,3-Dichloro-5,5-diphenyl-2,4-imidazolidinedione

Product:

β-chloro ketones

Catalyst:

2,5-Diphenyl-4,6-bis(9-O-dihydroquininyl)pyrimidine

Cas No:

149820-65-5

Associated Product from Buchler GmbH:

2,5-Diphenyl-4,6-bis(9-O-dihydroquininyl)pyrimidine

Cas No:

149820-65-5