Asymmetric dearomative cascade multiple functionalizations of activated N-alkylpyridinium and N-alkylquinolinium salts.
DOI Number:
10.1021/acs.orglett.0c02828
Reaction Category:
Educt:
N-alkylpyridinium salts, (E)-4-(2-hydroxyphenyl)but-3-en-2-one, (E)-4-(2-(phenylamino)phenyl)but-3-en-2-one
Product:
substituted (3aR,3a1S,6aR,11bR)-6-benzyl-3,3a,3a1,6,6a,11b-hexahydrochromeno[4,3,2-ij]isoquinolin-2(1H)-one
Catalyst:
3-methyl-D-Valine (9S)-6′-methoxycinchonan-9-yl ester
Cas No:
2515441-80-0
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0