Enantioselective Aza‐Henry Reaction of Seven‐Membered Cyclic Imines, Dibenzo [b,f][1,4] oxazepines, by Bifunctional Organocatalysis.

DOI Number:

10.1002/ejoc.201900151

Reaction Category:

RXNO ID:

RXNO_0000235

Educt:

substituted dibenzoxazepines, substituted dibenzothiazepines, nitromethane

Product:

substituted (R)-11-(nitromethyl)-10,11-dihydrodibenzo[b,f][1,4]oxazepine, substituted (R)-11-(nitromethyl)-10,11-dihydrodibenzo[b,f][1,4]thiazepine

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9R)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-22-5

Cas No:

130-95-0