Enantioselective Aza‐Henry Reaction of Seven‐Membered Cyclic Imines, Dibenzo [b,f][1,4] oxazepines, by Bifunctional Organocatalysis.
DOI Number:
10.1002/ejoc.201900151
Reaction Category:
Educt:
substituted dibenzoxazepines, substituted dibenzothiazepines, nitromethane
Product:
substituted (R)-11-(nitromethyl)-10,11-dihydrodibenzo[b,f][1,4]oxazepine, substituted (R)-11-(nitromethyl)-10,11-dihydrodibenzo[b,f][1,4]thiazepine
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9R)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-22-5
Associated Product from Buchler GmbH:
Quinine Base
Cas No:
130-95-0