Photocatalytic Z/E isomerization unlocking the stereodivergent construction of axially chiral alkene frameworks.
DOI Number:
10.1038/s41467-024-47404-3
Reaction Category:
Educt:
tert-butyl 2-(((tert-butoxycarbonyl)oxy)(phenyl)methyl)acrylate, 5-bromoquinolin-2(1H)-one
Product:
tert-butyl (Z)-3-(5-bromo-2-oxoquinolin-1(2H)-yl)-2-methyl-3-phenylacrylate
Catalyst:
(9S,9′′S)-9,9′′-[(2,5-diphenyl-4,6-pyrimidinediyl)bis(oxy)] bis[10,11-dihydro-6′-methoxy-cinchonan]
Cas No:
149725-81-5
Associated Product from Buchler GmbH:
Dihydroquinidine Base
Cas No:
1435-55-8