Enantioselective intermolecular C–H amination directed by a chiral cation.

DOI Number:

10.1021/jacs.1c05206
Link to literature

Reaction Category:

Amination

Educt:

2,2,3,3,4,4,4-heptafluorobutyl sulfamate, 4-phenylbutan-1-ol

Product:

2,2,3,3,4,4,4-heptafluorobutyl (R)-(4-hydroxy-1-phenylbutyl)sulfamate

Catalyst:

ruthenium(II), (9S)-1-[[3,5-bis(1,1-dimethylethyl)phenyl]methyl]-10,11-dihydro-9-hydroxy-6′-methoxy-cinchonanium bromide

Cas No:

1439215-88-9

Associated Product from Buchler GmbH:

Dihydroquinidine Base

Cas No:

1435-55-8