Highly enantioselective γ-amination of α,β-unsaturated acyl chlorides with azodicarboxylates: efficient synthesis of chiral γ-amino acid derivatives.
DOI Number:
10.1021/ja206819y
Reaction Category:
Educt:
α,β-unsaturated acyl chlorides, azodicarboxylates
Product:
di-tert-butyl (S)-3-oxo-3,5,6,7,8,8a-hexahydrocinnoline-1,2-dicarboxylate
Catalyst:
(9S)-6′-methoxy-9-[(trimethylsilyl)oxy]-cinchonan hydrochloride
Cas No:
931581-06-5
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2