Enantioselective Fluorination Mediated by Cinchona Alkaloid Derivatives/Selectfluor Combinations: Reaction Scope and Structural Information for N-Fluorocinchona Alkaloids.

DOI Number:

10.1021/ja010789t

Reaction Category:

MOP ID:

MOP_0000553

Educt:

((2-benzyl-1H-inden-3-yl)oxy)trimethylsilane, 1-(chloromethyl)-4-fluoro-1,4-Diazoniabicyclo[2.2.2]octane tetrafluoroborate

Product:

(R)-2-benzyl-2-fluoro-2,3-dihydro-1H-inden-1-one

Catalyst:

(R)-((1S,2S,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methyl 4-chlorobenzoate

Cas No:

113216-88-9

Cas No:

522-66-7