Exploiting Configurational Lability in Aza‐Sulfur Compounds for the Organocatalytic Enantioselective Synthesis of Sulfonimidamides.

DOI Number:

10.1002/ange.202109160
Link to literature

Reaction Category:

Alkylation | Alkylation | Desymmetrization

MOP ID:

MOP_0000369

Educt:

N,N'-bis(4-methoxybenzyl)-[1,1'-biphenyl]-4-sulfonimidamide, benzyl bromide

Product:

(S)-N-benzyl-N,N'-bis(4-methoxybenzyl)-[1,1'-biphenyl]-4-sulfonimidamide

Catalyst:

(9S)-1-[(4-cyanophenyl)methyl]-1′-[(2,5-difluorophenyl)methyl]-9-hydroxy-cinchonanium bromide (1:2)

Cas No:

2750217-42-4

Associated Product from Buchler GmbH:

Cinchonine Base

Cas No:

118-10-5