Stereoselective Organocatalyzed Synthesis of α‐Fluorinated β‐Amino Thioesters and Their Application in Peptide Synthesis.
DOI Number:
10.1002/ange.201607146
Reaction Category:
RXNO ID:
RXNO_0000016
Educt:
methyl 2-fluoro-3-((4-methoxyphenyl)thio)-3-oxopropanoate, 4-bromobenzaldehyde
Product:
S-(4-methoxyphenyl) (2S,3S)-3-(4-bromophenyl)-2-fluoro-3-hydroxypropanethioate
Catalyst:
N-[3,5-bis(trifluoromethyl)phenyl]-N′-[(9R)-6′-methoxycinchonan-9-yl]-urea
Cas No:
1326239-56-8
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2