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One-pot synthesis of α-diazo-β-hydroxyesters under phase-transfer catalysis and application to the catalytic asymmetric aldol reaction.
DOI Number:
10.1016/j.tetlet.2003.11.083
Link to literature
Reaction Category:
Aldol
|
Aldol
Educt:
1-naphthalenecarboxaldehyde, tert-butyl diazoacetate
Product:
1,1-dimethylethyl (βS)-α-diazo-β-hydroxybenzenepropanoate
Catalyst:
(8α,9R)- 1-(9-anthracenylmethyl)- 9-hydroxy-Cinchonanium chloride
Cas No:
199588-80-2
Associated Product from Buchler GmbH:
Cinchonidine Base
Cas No:
485-71-2