One-pot synthesis of α-diazo-β-hydroxyesters under phase-transfer catalysis and application to the catalytic asymmetric aldol reaction.

DOI Number:

10.1016/j.tetlet.2003.11.083
Link to literature

Reaction Category:

Aldol | Aldol

RXNO ID:

RXNO_0000016

Educt:

1-naphthalenecarboxaldehyde, tert-butyl diazoacetate

Product:

1,1-dimethylethyl (βS)-α-diazo-β-hydroxybenzenepropanoate

Catalyst:

(8α,9R)- 1-(9-anthracenylmethyl)- 9-hydroxy-Cinchonanium chloride

Cas No:

199588-80-2

Associated Product from Buchler GmbH:

Cinchonidine Base

Cas No:

485-71-2