Asymmetric Allylic Monofluoromethylation and Methylation of Morita–Baylis–Hillman Carbonates with FBSM and BSM by Cooperative Cinchona Alkaloid/FeCl2 Catalysis.
DOI Number:
10.1002/ange.201103748
Reaction Category:
MOP ID:
MOP_0000553
Educt:
methyl 2-(((tert-butoxycarbonyl)oxy)(3-chlorophenyl)methyl)acrylate, N-fluoro-N-(phenylsulfonyl)benzenesulfonamide
Product:
methyl 3-(3-chlorophenyl)-4-fluoro-2-methylene-4,4-bis(phenylsulfonyl)-3lambda3-butanoate
Catalyst:
1,4-Bis(9-O-dihydroquinidinyl)anthraquinone
Cas No:
176298-44-5
Associated Product from Buchler GmbH:
1,4-Bis(9-O-dihydroquinidinyl)anthraquinone
Cas No:
176298-44-5