Development of C-6′-modified quinine-derived phase-transfer catalysts and their application in the enantioselective α-hydroxylation of β-dicarbonyl compounds.
DOI Number:
10.1016/j.tetasy.2016.07.006
Reaction Category:
MOP ID:
MOP_0000673
Educt:
substituted 1-oxo-2,3-dihydro-1H-indene-2-carboxylate, substituted 1-oxo-2,3-dihydro-1H-indene-2-carboxamide, (2-hydroperoxypropan-2-yl)benzene
Product:
substituted 2-hydroxy-1-oxo-2,3-dihydro-1H-indene-2-carboxylate, substituted 2-hydroxy-1-oxo-2,3-dihydro-1H-indene-2-carboxamide
Catalyst:
(8α,9R)-1-[[4-fluoro-2-(trifluoromethyl)phenyl]methyl]-6′,9-dihydroxy-cinchonanium bromide
Cas No:
2374737-42-3
Associated Product from Buchler GmbH:
Cupreine Base
Cas No:
524-63-0