Silver-Catalyzed Enantioselective and Diastereoselective Aldol Reaction of α-Isocyanoacetates with Aldehydes Enabled by Cinchona-Derived Amide Adamantylphosphine Ligands.
DOI Number:
10.1021/acs.joc.5c02366
Reaction Category:
RXNO ID:
RXNO_0000016
Educt:
aldehydes, α-isocyanoacetates
Product:
substituted 4,5-dihydrooxazole-4-carboxylate
Catalyst:
silver oxide, 2-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N-[(9S)-6′-methoxycinchonan-9-yl]-benzamide
Cas No:
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2