Catalytic enantioselective synthesis of selenium-containing atropisomers via C–Se bond formations.

DOI Number:

10.3762/bjoc.21.186

Reaction Category:

Educt:

1-(phenylethynyl)naphthalen-2-ol, Se-phenyl benzenesulfonoselenoate

Product:

(E)-1-(2-phenyl-2-(phenylselanyl)-1-(phenylsulfonyl)vinyl)naphthalen-2-ol

Catalyst:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7

Associated Product from Buchler GmbH:

3-[[3,5-bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-6′-methoxycinchonan-9-yl]amino]-3-Cyclobutene-1,2-dione

Cas No:

1256245-84-7