Desymmetrization of Bisallylic Amides: A Catalytic Enantioselective Diastereoselective Chlorocyclization Strategy.

DOI Number:

10.1021/acs.orglett.5c01865
Link to literature

Reaction Category:

Chlorination | Cyclization | Cyclization | Desymmetrization | Further Cyclizations

MOP ID:

MOP_0000551

Educt:

bisallylic amides, N-chlorophthalimide

Product:

substitued 4-vinyl-5,6-dihydro-4H-1,3-oxazine

Catalyst:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine

Cas No:

140853-10-7

Associated Product from Buchler GmbH:

1,4-Bis(9-O-dihydroquinidinyl)phthalazine ((DHQD)2PHAL)

Cas No:

140853-10-7