Enantioselective synthesis of (R)-and (S)-α-alkylcysteines via phase-transfer catalytic alkylation.

DOI Number:

10.1021/jo061107t
Link to literature

Reaction Category:

Alkylation | alpha-Alkylation

MOP ID:

MOP_0000369

Educt:

2-substituted tert-butyl 4,5-dihydrothiazole-4-carboxylate, allyl bromide

Product:

substituted tert-butyl (S)-4-allyl-4,5-dihydrothiazole-4-carboxylate

Catalyst:

(8α,9R)-1-(9-anthracenylmethyl)-10,11-dihydro- 9-(2-propen-1-yloxy)-Cinchonanium bromide

Cas No:

550358-96-8

Associated Product from Buchler GmbH:

Dihydrocinchonidine Base

Cas No:

485-64-3