Organocatalytic enantioselective Michael addition of β-diketones to β-nitrostyrene: The first Michael addition of dipivaloylmethane to an activated olefin.

DOI Number:

10.3998/ark.5550190.0012.930

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

acetylaceton, β-nitrostyrene

Product:

3-(2-nitro-1-phenylethyl)pentane-2,4-dione

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7