Synthesis of ent-[3]-Ladderanol: development and application of intramolecular chirality transfer [2+2] cycloadditions of allenic ketones and alkenes.
DOI Number:
10.1021/jacs.7b09844
Reaction Category:
MOP ID:
MOP_0000563
Educt:
substituted 9-(silyloxy)non-1-en-7-yn-5-one
Product:
substituted (6S,8R)-8-((silyloxy)methyl)bicyclo[4.2.0]oct-1-en-3-one
Catalyst:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7
Associated Product from Buchler GmbH:
N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea
Cas No:
852913-16-7