Asymmetric reaction of p-quinone diimide: Organocatalyzed Michael addition of α-cyanoacetates.

DOI Number:

10.1021/acs.orglett.8b00771

Reaction Category:

MOP ID:

MOP_0000561

Educt:

p-quinone diimide, 3-substituted ethyl 2-cyano-propanoate

Product:

ethyl (S)-3-substituted-2-imino-5-((4-methylphenyl)sulfonamido)-1-tosylindoline-3-carboxylate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7