Regioselective and stereoselective cyclizations of cyclohexadienones tethered to active methylene groups.
DOI Number:
10.1039/C1OB06125A
Reaction Category:
Educt:
1-[1-(1,1-Dimethyl-3-buten-1-yl)-4-oxo-2,5-cyclohexadien-1-yl] 3-(1,1-dimethylethyl) propanedioate
Product:
rel-1,1-Dimethylethyl (3R,3aS,7aS)-7a-(1,1-dimethyl-3-buten-1-yl)-2,3,3a,4,5,7a-hexahydro-2,5-dioxo-3-benzofurancarboxylate
Catalyst:
ceasium carbonate, O-Allyl-1-(anthracen-9-ylmethyl)-cinchonidinium Bromide
Cas No:
200132-54-3
Associated Product from Buchler GmbH:
O-Allyl-1-(anthracen-9-ylmethyl)-cinchonidinium Bromide
Cas No:
200132-54-3