Enantioselective synthesis of epoxides having a tetrasubstituted trifluoromethylated carbon center: methylhydrazine-induced aerobic epoxidation of β,β-disubstituted enones.
DOI Number:
10.1002/anie.201209355
Reaction Category:
MOP ID:
MOP_0000671
Educt:
β-aryl-β-trifluoromethyl-disubstituted enones, oxygen
Product:
tetrasubstituted trifluoromethylated epoxides
Catalyst:
1-[[3,5-bis(trifluoromethyl)phenyl]methyl]-9-hydroxy-6′-methoxy-cinchonanium bromide
Cas No:
945732-76-3
Associated Product from Buchler GmbH:
N-3,5-Bis(trifluoromethyl)benzyl-quinidinium Bromide
Cas No:
945732-76-3