Diastereoselective aziridination of chiral electron-deficient olefins with N-chloro-N-sodiocarbamates catalyzed by chiral quaternary ammonium salts.
DOI Number:
10.1021/jo2010632
Reaction Category:
Educt:
1-((4R,7S)-7-isopropyl-4-methyl-3-phenyl-4,5,6,7-tetrahydro-1H-indazol-1-yl)prop-2-en-1-one, N-chloro-N-sodiocarbamates
Product:
benzyl (S)-2-((4R,7S)-7-isopropyl-4-methyl-3-phenyl-4,5,6,7-tetrahydro-1H-indazole-1-carbonyl)aziridine-1-carboxylate
Catalyst:
O-Allyl-1-(anthracen-9-ylmethyl)-cinchonidinium Bromide
Cas No:
200132-54-3
Associated Product from Buchler GmbH:
O-Allyl-1-(anthracen-9-ylmethyl)-cinchonidinium Bromide
Cas No:
200132-54-3