Stereoselective reaction of 2-carboxythioesters-1,3-dithiane with nitroalkenes: an organocatalytic strategy for the asymmetric addition of a glyoxylate anion equivalent.

DOI Number:

10.1039/C5OB00492F

Reaction Category:

RXNO ID:

RXNO_0000009

Educt:

2-carboxythioesters-1,3-dithiane, nitroalkenes

Product:

substituted S-(2,2,2-trifluoroethyl) 2-(2-nitroethyl)-1,3-dithiane-2-carbothioate

Catalyst:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7

Associated Product from Buchler GmbH:

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8α,9S)-6′-methoxycinchonan-9-yl]thiourea

Cas No:

852913-16-7