Diastereoselective and Enantioselective Epoxidation of Acyclic β‐Trifluoromethyl‐β,β‐Disubstituted Enones by Hydrogen Peroxide with a Pentafluorinated Quinidine‐Derived Phase‐Transfer Catalyst.
DOI Number:
10.1002/adsc.201300249
Reaction Category:
MOP ID:
MOP_0000671
Educt:
β-aryl-β-trifluoromethyl-disubstituted enones, hydroperoxide
Product:
tetrasubstituted trifluoromethylated epoxides
Catalyst:
(9S)-9-hydroxy-6′-methoxy-1-[(pentafluorophenyl)methyl]-cinchonanium bromide
Cas No:
231303-52-9
Associated Product from Buchler GmbH:
Quinidine Base
Cas No:
56-54-2