Photoinduced Copper-Catalyzed Enantioconvergent Remote Alkynylation via 1,4-Heteroaryl Migration.

DOI Number:

10.1021/acs.orglett.3c03158

Reaction Category:

Educt:

substituted methyl 2,2,5-trimethylhexanoate, primary alkynes

Product:

substituted 4,7,7-trimethyloct-2-yne

Catalyst:

copper(I)-catalyst, 2-[Bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-N-[(8α,9S)-6′-methoxycinchonan-9-yl]benzamide

Cas No:

2389028-68-4

Cas No:

130-95-0